Porous BMTTPA-CS-GO nanocomposite for the efficient removal of heavy metal ions from aqueous solutions

In this study, a stable, cost-effective and environmentally friendly porous 2,5-bis(methylthio)terephthalaldehyde-chitosan-grafted graphene oxide (BMTTPA-CS-GO) nanocomposite was synthesized by covalently grafting BMTTPA-CS onto the surfaces of graphene oxide and used for removing heavy metal ions from polluted water. According to well-established Hg²⁺-thioether coordination chemistry, the newly designed covalently linked stable porous BMTTPA-CS-GO nanocomposite with thioether units on the pore walls greatly increases the adsorption capacity of Hg²⁺ and does not cause secondary pollution to the environment. The results of sorption experiments and inductively coupled plasma mass spectrometry measurements demonstrate that the maximum adsorption capacity of Hg²⁺ on BMTTPA-CS-GO at pH 7 is 306.8 mg g^-1, indicating that BMTTPA-CS-GO has excellent adsorption performance for Hg²⁺. The experimental results show that this stable, environmentally friendly, cost-effective and excellent adsorption performance of BMTTPA-CS-GO makes it a potential nanocomposite for removing Hg²⁺ and other heavy metal ions from polluted water, and even drinking water. This study suggests that covalently linked crucial groups on the surface of carbon-based materials are essential for improving the adsorption capacity of adsorbents for heavy metal ions.