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Enhancing the photocatalytic hydrogen production activity of BiVO4 [110] facets using oxygen vacancies
Jing Pan1, Xiaoxue Ma1, Wannian Zhang1
1College of Physics Science and Technology, Yangzhou University Yangzhou 225002 China jghu@yzu.edu.cn.
Abstract:
The activity of the hydrogen evolution reaction (HER) during photoelectrochemical (PEC) water-splitting is limited when using BiVO4 with an exposed [110] facet because the conduction band minimum is below the H+/H2O potential. Here, we enhance the photocatalytic hydrogen production activity through introducing an oxygen vacancy. Our first-principles calculations show that the oxygen vacancy can tune the band edge positions of the [110] facet, originating from an induced internal electric field related to geometry distortion and charge rearrangement. Furthermore, the induced electric field favors photogenerated electron-hole separation and the enhancement of atomic activity. More importantly, oxygen-vacancy-induced electronic states can increase the probability of photogenerated electron transitions, thus improving optical absorption. This study indicates that oxygen-defect engineering is an effective method for improving the photocatalytic activity when using PEC technology.
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