Related Experiment Video
Updated: Sep 26, 2025

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Solution to the Fokker-Planck equation for slowly driven Brownian motion: Emergent geometry and a formula for the
Neha S Wadia1, Ryan V Zarcone1, Michael R DeWeese1,2,3
1Biophysics Graduate Group, University of California at Berkeley, Berkeley, California 94720, USA.
Abstract:
Considerable progress has recently been made with geometrical approaches to understanding and controlling small out-of-equilibrium systems, but a mathematically rigorous foundation for these methods has been lacking. Towards this end, we develop a perturbative solution to the Fokker-Planck equation for one-dimensional driven Brownian motion in the overdamped limit enabled by the spectral properties of the corresponding single-particle Schrödinger operator. The perturbation theory is in powers of the inverse characteristic timescale of variation of the fastest varying control parameter, measured in units of the system timescale, which is set by the smallest eigenvalue of the corresponding Schrödinger operator. It applies to any Brownian system for which the Schrödinger operator has a confining potential. We use the theory to rigorously derive an exact formula for a Riemannian "thermodynamic" metric in the space of control parameters of the system. We show that up to second-order terms in the perturbation theory, optimal dissipation-minimizing driving protocols minimize the length defined by this metric. We also show that a previously proposed metric is calculable from our exact formula with corrections that are exponentially suppressed in a characteristic length scale. We illustrate our formula using the two-dimensional example of a harmonic oscillator with time-dependent spring constant in a time-dependent electric field. Lastly, we demonstrate that the Riemannian geometric structure of the optimal control problem is emergent; it derives from the form of the perturbative expansion for the probability density and persists to all orders of the expansion.
Related Concept Videos
Maxwell-Boltzmann Distribution: Problem Solving
This distribution function f(v) is defined by saying that the expected number N (v1,v2) of particles with speeds between v1 and v2 is given by
Mean free path and Mean free time
Distribution of Molecular Speeds
Maxwell's Thermodynamic Relations
All thermodynamic potentials are exact differentials. Therefore, their second-order...
Euler's Equations of Motion
Bernoulli's Equation

