Ag-Bi Charge Redistribution Creates Deep Traps in Defective Cs₂AgBiBr₆: Machine Learning Analysis of Density...

Lead-free double perovskites hold promise for stable and environmentally benign solar cells; however, they exhibit low efficiencies because defects act as charge recombination centers. Identifying trap-assisted loss mechanisms and developing defect passivation strategies constitute an urgent goal. Applying unsupervised machine learning to density functional theory and nonadiabatic molecular dynamics, we demonstrate that negatively charged Br vacancies in Cs₂AgBiBr₆ create deep hole traps through charge redistribution between the adjacent Ag and Bi atoms. Vacancy electrons are first accepted by Bi and then shared with Ag, as the trap transforms from shallow to deep. Subsequent charge losses are promoted by Ag and Bi motions perpendicular to rather than along the Ag-Bi axis, as can be expected. In contrast, charge recombination in pristine Cs₂AgBiBr₆ correlates most with displacements of Cs atoms and Br-Br-Br angles. Doping with In to replace Ag at the vacancy maintains the electrons at Bi and keeps the trap shallow.