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Updated: Sep 26, 2025

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Ordered structure constructed from C2-symmetric hexa-peri-hexabenzocoronene linked with oligo(dimethylsiloxane)
Wei Zhang1, Weilu Yang1, Hongbing Pan1
1Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, and College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China. zshen@pku.edu.cn.
Abstract:
The preparation of sub-5-nm ordered structures is very important to the development of today's nanotechnology. Block molecules have the potential to form structures with significantly small characteristic dimensions. Herein two novel organic-inorganic block molecules composed of a hexa-peri-hexabenzocoronene (HBC) core and two oligo(dimethylsiloxane) (ODMS) tails with C2 symmetry are reported. A hierarchical lamello-columnar structure with a two-dimensional rectangular lattice where HBC cores adopt a tilted arrangement was obtained from their bulk self-assembly. The feature sizes are all below 5 nm and can be regulated via the number of ODMS chains. Sub-5-nm line structures were obtained through spin-coating of the block molecules onto silicon substrates modified with poly(dimethylsiloxane). As organic-inorganic hybrid materials, these block molecules may be further applied in sub-5-nm nanopatterning.
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