Epitaxial Orientation Angle Tuned Disk-on-Rod Nanoheterostructures for Boosting Charge Transfer

Controlling the compositions of Se(VI) and Te(VI) ions in a 2D disk on 1D structures of Sb(V) chalcogenides, disk-on-rod heterostructures having three different epitaxial angles with different surface facets are reported. Te injection temperature determined the composition, ensuring heterostructure formation with trigonal Sb₂SeTe_3- disks on orthorhombic Sb₂Se₃ rods having orientation angles 180°, 135°, and 90°. The growth kinetics of disks connected at one/two heads of parent rods is manipulated using an Se precursor as a limiting reagent. Theoretical calculations established the energy minimization of different orientations, their possible formation, and suitability in energy transfer applications. Electrochemical measurements were also in agreement with theoretical calculations. Hence, this is a case study of advanced modular synthesis of disk-on-rod nanostructures, leading a step further in nanocrystal engineering for more desirable complex structures and their charge transfer property.