Synthesis, Structural, and Mechanical Behavior of β-Ca₃(PO₄)₂-ZrO₂ Composites Induced by Elevated Thermal Treatments

Biocompatible β-Ca₃(PO₄)₂ and mechanically stable t-ZrO₂ composites are currently being combined to overcome the demerits of the individual components. A series of five composites were synthesized using an aqueous precipitation technique. Their structural and mechanical stability was examined through X-ray diffraction, Rietveld refinement, FTIR, Raman spectroscopy, high-resolution scanning electron microscopy, and nanoindentation. The characterization results confirmed the formation of β-Ca₃(PO₄)₂-t-ZrO₂ composites at 1100 °C. Heat treatment above 900 °C resulted in the degradation of the composites because of cationic interdiffusion between Ca²⁺ ions and O^-2 vacancy in Zr⁴⁺ ions. Sequential thermal treatments correspond to four different fractional phases: calcium-deficient apatite, β-Ca₃(PO₄)₂, t-ZrO₂, and m-ZrO₂. The morphological features confirm in situ synthesis, which reveals abnormal grain growth with voids caused by the upsurge in ZrO₂ content. The mechanical stability data indicate significant variation in Young's modulus and hardness throughout the composite.