Related Experiment Video
Updated: Sep 26, 2025

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Quantum Coherences and Classical Inhomogeneities as Equivalent Thermodynamics Resources
Andrew Smith1, Kanupriya Sinha2,3, Christopher Jarzynski1,4,5
1Department of Physics, University of Maryland, College Park, MD 20742, USA.
Abstract:
Quantum energy coherences represent a thermodynamic resource, which can be exploited to extract energy from a thermal reservoir and deliver that energy as work. We argue that there exists a closely analogous classical thermodynamic resource, namely, energy-shell inhomogeneities in the phase space distribution of a system's initial state. We compare the amount of work that can be obtained from quantum coherences with the amount that can be obtained from classical inhomogeneities, and find them to be equal in the semiclassical limit. We thus conclude that coherences do not provide a unique thermodynamic advantage of quantum systems over classical systems, in situations where a well-defined semiclassical correspondence exists.
Related Concept Videos
Entropy and the Second Law of Thermodynamics
The relation between entropy and disorder can be illustrated with the example of the phase change of ice to water. In ice, the molecules are located at specific sites giving a solid state, whereas, in a liquid form, these molecules are much freer to move. The molecular arrangement has therefore become more randomized. Although the change in average...
Statements of the Second Law of Thermodynamics
Zeroth Law of Thermodynamics
Thermodynamic Systems
Consider an example of tea boiling in a kettle. The...
First Law of Thermodynamics
The applied heat increases the internal energy of a system. Hence, conventionally heat is considered...
Thermodynamic Potentials

