1D-on-1D core-shell cobalt iron selenide @ cobalt nickel carbonate hydroxide hybrid nanowire arrays as advanced...

Sluggish kinetics and poor structural stability are two main obstacles hampering the exploration of transition metal selenides (TMSs) for supercapacitor. Developing a reasonable core-shell heterostructure with unique morphology is an effective approach to resolve these issues. Herein, a core-shell cobalt iron selenide (CoFe₂Se₄) @ cobalt nickel carbonate hydroxide (CoNi-CH) heterostructure is directly fabricated on carbon cloth via an electrodeposition method followed by a hydrothermal reaction. In this well-defined heterostructure, one-dimensional (1D) CoFe₂Se₄ nanowires function as the cores and CoNi-CH nanowires as the shells, which combines the merits of highly conductive CoFe₂Se₄ for rapid electron transfer and highly electroactive CoNi-CH for multiple redox reactions. Further, the intimate interaction between CoNi-CH and CoFe₂Se₄ realizes large surface area with hierarchical network and generates rich heterointerfaces with modified the electronic structure. By virtue of its facile 1D-on-1D nanoarchitecture and synergistic effect, the CoFe₂Se₄@CoNi-CH electrode delivers a increased specific capacity of 218.6 mAh g^-1 at 1 A^-1 and enhanced rate capability (65.5% at 20 A g^-1) compared with pure CoFe₂Se₄ and CoNi-CH. Besides, a hybrid supercapacitor is established by coupling CoFe₂Se₄@CoNi-CH cathode and porous carbon anode, which enjoys a maximum energy density of 67.3 Wh kg^-1 at 765.9 W kg^-1 and prominent durability with 85.4% of capacity retention over 20,000 cycles.