Ultrafine cobalt selenide nanowires tangled with MXene nanosheets as highly efficient electrocatalysts toward the...

Hydrogen energy has attracted sustainable attention in the exploitation and application of advanced power-generator devices, and electrocatalysts for the hydrogen evolution reaction (HER) have been regarded as one of the core components in the current electrochemical hydrogen production systems. In this work, a facile and cost-effective bottom-up strategy is developed for the construction of 1D ultrafine cobalt selenide nanowires tangled with 2D Ti₃C₂T MXene nanosheets (CoSe NW/Ti₃C₂T) through an in situ stereo-assembly process. Such an architectural design endows the hybrid system not only with a large accessible surface for the rapid transportation of reactants, but also with numerous exposed CoSe edge sites, thereby generating substantial synergic coupling effects. The as-derived CoSe NW/Ti₃C₂T hybrid demonstrates competitive electrocatalytic properties toward the HER with a small onset potential of 84 mV, a low Tafel slope of 56 mV dec^-1 and exceptional cycling performance, which are superior to those of bare CoSe and Ti₃C₂T materials. It is believed this promising nanoarchitecture may provide new possibilities for the design and construction of precious-metal-free electrocatalysts with high efficiency and great stability in the energy-conversion field.