Photodegradation of pesticides using compound-specific isotope analysis (CSIA): a review

Pesticides are commonly applied in agriculture to protect crops from pests, weeds, and harmful pathogens. However, chronic, low-level exposure to pesticides can be toxic to humans. Photochemical degradation of pesticides in water, soil, and other environmental media can alter their environmental fate and toxicity. Compound-specific isotope analysis (CSIA) is an advanced diagnostic tool to quantify the degradation of organic pollutants and provide insight into reaction mechanisms without the need to identify transformation products. CSIA allows for the direct quantification of organic degradation, including pesticides. This review summarizes the recent developments observed in photodegradation studies on different categories of pesticides using CSIA technology. Only seven pesticides have been studied using photodegradation, and these studies have mostly occurred in the last five years. Knowledge gaps in the current literature, as well as potential approaches for CSIA technology for pesticide monitoring, are discussed in this review. Furthermore, the CSIA analytical method is challenged by chemical element types, the accuracy of instrument analysis, reaction conditions, and the stability of degradation products. Finally, future research applications and the operability of this method are also discussed.