Enhancement of exchangeable Cd and Pb immobilization in contaminated soil using Mg/Al LDH-zeolite as an effective...

In the present study, experiments using zeolite and Mg/Al LDH-zeolite for immobilization of Cd and Pb ions in artificial soil were conducted. The conditions which affect Cd and Pb ion immobilization in soil were evaluated, namely soil pH (5-7), the mass ratio of adsorbents (1%, 3% and 5%), incubation time (15 days, 30 days and 45 days) and soil moisture (30%, 50% and 70%). The results indicated that the optimal soil pH, mass ratio of adsorbents, incubation time and soil moisture for immobilization of Cd and Pb ions by the adsorbent were, respectively, 7.0, 3%, 30 days and 70%. The exchangeable Cd ion content in the contaminated soil dropped from 22.17 mg kg^-1 (87.65%) to 11.03 mg kg^-1 (43.48%) and 6.47 mg kg^-1 (26.36%) on incubation with zeolite and Mg/Al LDH-zeolite, respectively, while the exchangeable Pb content fell from 23.28 mg kg^-1 (90.02%) to 14.12 mg kg^-1 (54.04%) and 9.47 mg kg^-1 (35.24%) using zeolite and Mg/Al LDH-zeolite as absorbents in contaminated soil, respectively. Fe-Mn oxide occluded (F2), carbonate bound (F3) and organically complexed (F4) were the main forms for immobilization of the exchangeable Cd and Pb when the zeolite and Mg/Al LDH-zeolite absorbents were separately cultivated into soil. Precipitation, co-precipitation and electrostatic attraction were the main mechanisms of exchangeable Cd and Pb immobilization onto the Mg/Al LDH-zeolite to form carbonate metals (CdCO₃ and PbCO₃). This was due to the surface functional groups of the adsorbent and the presence of Fe and Al oxyhydroxides, Mn oxides, and Si and O elements in the Mg/Al LDH-zeolite's constituents. The efficiency of Cd and Pb immobilization by the Mg/Al LDH-zeolite was higher than that by zeolite from 1.5 to 1.6 times. The Mg/Al LDH-zeolite showed an enhanced ability of exchangeable Cd and Pb immobilization in contaminated soil.