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MOS Capacitor01:25

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A Metal-Oxide-Semiconductor (MOS) capacitor is a fundamental structure used extensively in semiconductor device technology, particularly in the fabrication of integrated circuits and MOSFETs (metal-oxide-semiconductor field-effect transistors). The MOS capacitor consists of three layers: a metal gate, a dielectric oxide, and a semiconductor substrate.
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Plastic Monolithic Mixed-Conducting Interlayer for Dendrite-Free Solid-State Batteries.

Bing-Qing Xiong1, Shunqiang Chen1, Xuan Luo1

  • 1Department of Materials Science and Engineering, School of Chemistry and Materials Science, University of Science and Technology of China, Anhui, 230026, China.

Advanced Science (Weinheim, Baden-Wurttemberg, Germany)
|April 29, 2022
PubMed
Summary
This summary is machine-generated.

A new plastic monolithic mixed-conducting interlayer (PMMCI) prevents lithium dendrites in solid-state batteries. This material ensures uniform lithium plating and stripping, enhancing battery safety and performance.

Keywords:
dendrite-freelithium aromatic hydrocarbon complexmixed-conducting interlayersolid-solid interfacesolid-state electrolyte

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • Solid-state electrolytes (SSEs) are crucial for high-energy-density, safe rechargeable batteries.
  • Nonuniform lithium deposition and dendrite penetration at the solid-solid interface limit practical applications.

Purpose of the Study:

  • To introduce a novel plastic monolithic mixed-conducting interlayer (PMMCI) for solid-state batteries.
  • To improve interfacial contact and ion/electron transport between Li metal anodes and garnet electrolytes.

Main Methods:

  • A facile cold process was used to fabricate a solid-state lithium naphthalenide (Li-Naph(s)) PMMCI.
  • Characterization of the PMMCI's crystalline structure and mixed-conducting properties (Li+ and electron conductivity).
  • Testing of Li symmetric cells with PMMCI-modified garnet electrolytes under various current densities.

Main Results:

  • The PMMCI exhibits a well-ordered layered structure with significant Li+ (4.38 × 10-3 S cm-1) and electron (1.01 × 10-3 S cm-1) conductivity.
  • The monolithic interlayer enabled homogenous electric field and Li+ transport, reducing interfacial resistance.
  • Li symmetric cells demonstrated stable cycling for 1200 h at 0.2 mA cm-2 and 500 h at 1 mA cm-2.

Conclusions:

  • The PMMCI effectively suppresses lithium dendrites and promotes uniform Li anode plating/stripping.
  • This work presents a new interface design strategy for solid-state batteries using monolithic interlayers.
  • The developed PMMCI enhances the safety and cycling stability of Li metal solid-state batteries.