The heteroaggregation and deposition behavior of nanoplastics on Al₂O₃ in aquatic environments

The ubiquitous Al₂O₃ is anticipated to interact with nanoplastics, affecting their fate and transport in aquatic environments. In this study, the heteroaggregation and deposition behaviors of polystyrene nanoplastics (PSNPs) on Al₂O₃ were systematically investigated under different conditions (ionic strength, pH, and natural organic matter). The results showed that significant heteroaggregation occurred between PSNPs and Al₂O₃ particles under acidic and neutral conditions. When the NaCl concentration was increased from 50 to 500 mM, the heteroaggregation ratio gradually increased. However, poly (acrylic acid) (PAA) inhibited the heteroaggregation of PSNPs-Al₂O₃ due to steric repulsion. The deposition of PSNPs on Al₂O₃ surfaces was inhibited as the NaCl concentration or pH values increased. Due to charge reversal and steric repulsion, humic acid (HA) and fulvic acid (FA) prevented the deposition of PSNPs onto Al₂O₃ surfaces, and the former was more effective in reducing the deposition rate. The interaction mechanism between PSNPs and Al₂O₃ was revealed by using various characterization techniques and density function theory (DFT) calculation. The results demonstrated that in addition to the dominant electrostatic interaction, there were also weak hydrogen bonds and van der Waals interactions. Our research is of great significance for predicting the migration and fate of PSNPs in aquatic environments.