Related Experiment Video
Updated: Sep 25, 2025
Preparation of Biomass-based Mesoporous Carbon with Higher Nitrogen-/Oxygen-chelating Adsorption for CuII Through Microwave Pre-Pyrolysis
Published on: February 12, 2019
Suppression of polycyclic aromatic hydrocarbon formation during pyrolytic production of lignin-based biochar via
Chang-Mao Hung1, Chiu-Wen Chen1, Chin-Pao Huang2
1Department of Marine Environmental Engineering, National Kaohsiung University of Science and Technology, Kaohsiung City, Taiwan.
Abstract:
Polycyclic aromatic hydrocarbons are toxic byproducts of biochar production. The effects of pyrolysis atmosphere (i.e., N2 and CO2) and temperature (i.e., 300-900 °C) and element doping (i.e., N, B, O, and S) on the production of sixteen high priority polycyclic aromatic hydrocarbons in lignin-based biochar was investigated. N2 atmosphere at 300 °C produced the highest total polycyclic aromatic hydrocarbon content (1698 ± 50 ng/g). Polycyclic aromatic hydrocarbon formation decreased with increase in temperature (31 ± 15 ng/g at 900 °C). CO2 atmosphere significantly decreased yield of polycyclic aromatic hydrocarbons. The effects of heteroatom doping on polycyclic aromatic hydrocarbon formation were investigated for the first time in the pyrolysis synthesis of lignin-based biochar. N-, B-, O, N-B-, and N-S-doping of biochar reduced polycyclic aromatic hydrocarbon formation by 90, 85, 87, 97, and 89%, respectively. Results bring new insights into the role of heteroatom-doping and pyrolysis conditions in controlling polycyclic aromatic hydrocarbon formation in biochars.
More Related Videos
Related Concept Videos
02:47Alkynes to Aldehydes and Ketones: Hydroboration-Oxidation
One of the convenient methods for the preparation of aldehydes and ketones is via hydration of alkynes. Hydroboration-oxidation of alkynes is an indirect hydration reaction in which an alkyne is treated with borane followed by oxidation with alkaline peroxide to form an enol that rapidly converts into an aldehyde or a ketone. Terminal alkynes form aldehydes, whereas internal alkynes give ketones as the final product.
02:36Regioselectivity and Stereochemistry of Hydroboration
Hydroboration proceeds in a concerted fashion with the attack of borane on the π bond, giving a cyclic four-centered transition state. The –BH2 group is bonded to the less substituted carbon and –H to the more substituted carbon. The concerted nature requires the simultaneous addition of –H and –BH2 across the same face of the alkene giving syn...