Crystal structure and Hirshfeld surface analysis of tris-(acetohydrazide-κ2 N,O)(nitrato-κO)(nitrato-κ2 O,O')terbium(III) nitrate
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Updated: Sep 25, 2025
Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Chatphorn Theppitak1, Sakchai Laksee2, Kittipong Chainok1
1Thammasat University Research Unit in Multifunctional Crystalline Materials and Applications (TU-McMa), Faculty of Science and Technology, Thammasat University, Khlong Luang, Pathum Thani, 12121, Thailand.
Abstract:
In the title lanthanide(III) compound, [Tb(NO3)2(C2H6N2O)3]NO3, the asym-metric unit contains one Tb3+ ion, three acetohydrazide (C2H6N2O) ligands, two coordinated nitrate anions, and an isolated nitrate anion. The Tb3+ ion is in a ninefold coordinated distorted tricapped trigonal-prismatic geometry formed by three oxygen atoms and three nitro-gen atoms from three different acetohydrazide ligands and three oxygen atoms from two nitrate anions. In the crystal, the complex mol-ecules and the non-coordinated nitrate anions are assembled into a three-dimensional supra-molecular architecture through extensive N-H⋯O hydrogen-bonding inter-actions between the amine NH groups of the acetohydrazide ligands and the nitrate oxygen atoms. Hirshfeld surface analysis was performed to aid in the visualization of inter-mol-ecular contacts.
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