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Updated: Sep 25, 2025

Low-energy Cathodoluminescence for OxyNitride Phosphors
Published on: November 15, 2016
The interesting luminescence behavior and rare nonlinear optical properties of the {Ag55Mo6} nanocluster
Kun Zhou1,2, Li-Kai Yan1, Yun Geng1
1Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University Changchun 130024 Jilin China gengy575@nenu.edu.cn wangxl824@nenu.edu.cn.
Abstract:
The remarkably reversible thermochromic luminescence behavior and the rare nonlinear optical (NLO) properties of the [Ag55(MoO4)6(C[triple bond, length as m-dash]C Bu)24(CH3COO)18(CH3COO)]·2H2O ({Ag55Mo6} for short) nanocluster reported were investigated experimentally. The important contributions of Ag+, C[triple bond, length as m-dash]C- ions and MoO4 2- groups to the NLO properties were proved by further density functional theory (DFT) calculations.
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