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Updated: Sep 25, 2025

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
Published on: December 16, 2022
Synthesis of thermoresponsive oligo(ethylene glycol) polymers through radical ring-opening polymerization of
Jovana Stanojkovic1, Junki Oh2, Anzar Khan2
1Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University 21-Nanyang Link 637371 Singapore mstuparu@ntu.edu.sg.
Abstract:
Polyvinylcyclopropanes are an old class of polymers typically known for their low polymerization-induced shrinkage properties. In this work, we show that they are capable of exhibiting a thermally triggered aggregation process in aqueous solutions. The phase transition is sharp, tunable within the temperature range of 25-46 °C, and relatively insensitive to environmental conditions. It is anticipated that this preliminary study will shine new light on polyvinylcyclopropanes and lead to new avenues in their studies and future application.
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