Ag₂O-decorated electrospun BiVO₄ nanofibers with enhanced photocatalytic performance

Semiconductor photocatalysts are emerging as tools for pollutant degradation in industrial wastewater, air purification, antibacterial applications, etc. due to their use of visible light, which is abundant in sunlight. Here, we report a new type of p-n junction Ag₂O/BiVO₄ heterogeneous nanostructured photocatalyst with enhanced photocatalytic performance. P-type Ag₂O nanoparticles were in situ reduced and assembled on the surface of electrospun BiVO₄ nanofibers using ultraviolet (UV) irradiation; this process hindered the recombination of localized photogenerated electron-hole pairs, and hence resulted in the enhanced photocatalytic activity of the BiVO₄/Ag₂O nanocomposites. The photocatalytic activities of the obtained BiVO₄ and BiVO₄/Ag₂O nanocomposites were assessed by measuring the degradation of rhodamine B (RhB) under visible light. The 10 wt% Ag₂O/BiVO₄ sample yielded the optimum degradation of RhB (98.47%), much higher than that yielded by pure BiVO₄ nanofibers (64.67%). No obvious change in the XRD pattern of an Ag₂O/BiVO₄ sample occurred as a result of its use in the photocatalytic reaction, indicating its excellent stability. The high photocatalytic performance observed was attributed to the large surface-to-volume ratio of the essentially one-dimensional electrospun BiVO₄ nanofibers and to the in situ growth of p-type Ag₂O on the surface of the n-type BiVO₄ nanofibers.