Anisotropic dynamics of resonant scattering between a pair of cold aligned diatoms

The collision dynamics between a pair of aligned molecules in the presence of a partial-wave resonance provide the most sensitive probe of the long-range anisotropic forces important to chemical reactions. Here we control the collision temperature and geometry to probe the dynamics of cold (1-3 K) rotationally inelastic scattering of a pair of optically state-prepared D₂ molecules. The collision temperature is manipulated by combining the gating action of laser state preparation and detection with the velocity dispersion of the molecular beam. When the bond axes of both molecules are aligned parallel to the collision velocity, the scattering rate drops by a factor of 3.5 as collision energies >2.1 K are removed, suggesting a geometry-dependent resonance. Partial-wave analysis of the measured angular distribution supports a shape resonance within the centrifugal barrier of the l = 2 incoming orbital. Our experiment illustrates the strong anisotropy of the quadrupole-quadrupole interaction that controls the dynamics of resonant scattering.