Related Experiment Video
Updated: Sep 24, 2025
Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
Electrostatic attraction induces cationic covalent-organic framework to pack inorganic acid ions for promoting proton
Xiao-Fei Liu1, Sheng-Zheng Huang2, Yu-Xiang Lian2
1College of Chemistry, Zhengzhou University, Zhengzhou 450001, China. zangsqzg@zzu.edu.cn.
Abstract:
A cationic COF (CCOF) was imported to afford stable proton conductive material while the positively charged CCOF can constrain the inorganic anion groups into the framework through an ion exchange process. The inorganic anions could play the role of proton donors to provide a rich source of protons, as well as the proton acceptors for proton transmission, thus forming an interlinked proton conduction pathway within the framework. The proton conductivities of COF materials loaded with different anions have been improved to varying degrees, and the conductivity of H2PO4-@CCOF is up to 3.86 × 10-2 S cm-1 at 100 °C.
More Related Videos
Related Concept Videos
02:48Ionic Bonding and Electron Transfer
02:54Ions as Acids and Bases
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
03:13Intermolecular Forces
03:45Formation of Complex Ions
00:42Ionic Bonds
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
03:05Acid Strength and Molecular Structure
In the absence of any leveling effect, the acid strength of binary compounds of hydrogen with nonmetals (A) increases as the H-A bond strength decreases down a group in the periodic table. For group 17, the order of increasing acidity is HF < HCl < HBr < HI. Likewise, for group 16, the order of increasing acid strength is H2O < H2S < H2Se < H2Te. Across a row in the periodic table, the acid strength of binary hydrogen compounds increases with...