Recirculation of activated sludge for coagulant synthesis under hydrothermal conditions

A hypothesis was proposed that the activated sludge was converted into hydrochar full of phenolic hydroxyl and then was made into coagulant by graft copolymerization. The results show that under the addition of HCl, the content of phenolic hydroxyl on the surface of hydrochar (SBC) under hydrothermal conditions increased sharply, up to 1.586 mmol/g, showing that HCl dosage of 0.10 g/g _{dry sludge} and holding time of 4 h was recommended. Under graft copolymerization with the addition of DMC, the coagulant was synthesized. Based on the analysis by FTIR, XPS, zeta potential, etc., the possible synthesis route of coagulant from SBC was that phenolic hydroxyl on SBC was activated by the initiator and then the polymerization between SBC and DMC was triggered. The optimal grafting conditions are gotten. It was named as SBC_{HCl0.10 g, 4 h}-g-DMC_0.7. The removal by SBC_{HCl0.10 g, 4 h}-g-DMC_0.7 on COD and turbidity in domestic wastewater is up to 69% and 93%, respectively. The component of COD indicated that almost all particulate COD and most of colloidal COD are removed. On the contrary, the removal on dissolved COD can be neglected. Most of NH₃-N and P is kept in the wastewater. This is in favor of subsequent reuse and biological treatment.