Photoelectrochemical oxygen evolution with interdigitated array electrodes: the example of TiO₂

The catalytic reactions of photoelectrochemical water splitting attracts tremendous attention as a promising strategy for clean energy production. And the research on reaction mechanism is particularly important in design and developing new catalysts. In this work, the special electrochemical tool of interdigitated array (IDA) electrodes was utilized in investigating the photoelectrochemical oxygen evolution reaction process and detecting the reaction productin situwith the generation-collection mode. TiO₂was taken as a model catalyst and was decorated onto the IDA generator electrode through an electrophoresis method, so that the photoelectrochemical water splitting can take place on the IDA generator and the reaction product can be detected directly with the IDA collector in real time. It is found that TiO₂can be successfully decorated onto the surface of IDA electrode with the expected photoelectrochemical activity, and the generation-collection mode reveals and distinguishes the production of O₂from the overall photoelectrochemical current on TiO₂generator. The mass transfer process of O₂from the TiO₂generator to the collector could be observed as well. Large overall current at high potential range indicates the possible increasing production of the byproducts or nonfaradaic current.