Carbon nanotube-passive samplers as novel tools for sampling and determining micropollutants in the aquatic...

Passive sampling is an interesting and cost-effective strategy for the quantification of micropollutants in the aquatic environment. When combined especially with a sensitive analytical method such as liquid chromatography coupled with triple quadrupole mass spectrometry (LC-MS/MS), the use of passive sampling devices (PSDs) enables long-term and reliable determination of a wide range of chemicals. In this study, carbon nanotubes (CNTs) were used as an innovative sorbent in POCIS-like samplers (Polar Organic Chemical Integrative Sampler). The developed CNTs-PSDs were calibrated by the flow-through method and the obtained sampling rates (R_s) of analytes were compared with the previously obtained R_s values using the semi-static method. Subsequently, passive samplers were placed in the Baltic Sea, the Nogat River, and the Sztumskie Pole Lake in order to sample and concentrate 28 chemical compounds belonging to the group of contaminants of emerging concern (CECs). For the first time, the effectiveness of the use of CNTs-PSDs in the field was proven by the quantification of carbamazepine, diclofenac, p-nitrophenol, bisphenol A, 3,5-dichlorophenol, 17-β-estradiol, 17-α-ethinylestradiol and metoprolol in the tested surface waters. The obtained time-weighted average (TWA) concentrations of analytes ranged from 0.22 ± 0.12 ng/L (for metoprolol in the Nogat River) to 32.1 ± 2.4 ng/L (for bisphenol A in the Sztumskie Pole Lake). More importantly, CNTs-PSDs determined a greater amount of micropollutants than grab sampling and solid-phase extraction (SPE), which proves the advantage of passive sampling over grab sampling, especially when monitoring contaminants in the aquatic environment at low concentration levels.