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Aquaporins or AQPs are a family of integral membrane proteins whose primary function is to transport water, while some called aquaglyceroporins also transport glycerol. In addition, aquaporins have also been suspected to be involved in transporting volatile substances, such as carbon dioxide and ammonia, across membranes. Such AQPs that act as gas channels are often highly expressed in cells involved in the gaseous exchange, such as red blood cells, epithelial cells, and pulmonary capillaries.
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Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
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Poly(ionic liquid)-Armored MXene Membrane: Interlayer Engineering for Facilitated Water Transport.

Ming Yi1,2,3, Mi Wang4, Yan Wang1,2

  • 1Key Laboratory of Material Chemistry for Energy Conversion and Storage, Huazhong University of Science and Technology, Wuhan, 430074, P. R. China.

Angewandte Chemie (International Ed. in English)
|May 3, 2022
PubMed
Summary

This study developed tunable MXene membranes for water purification. Modifying hydrophilicity via poly(ionic liquid)s significantly improved water permeance and rejection for advanced filtration.

Keywords:
Anion ExchangeAssemblyMXeneNanochannel HydrophilicityPoly(Ionic Liquid)

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Environmental Science

Background:

  • Two-dimensional (2D) MXene-based lamellar membranes show potential for water purification.
  • Engineering surface properties in subnanoconfinement for high selectivity remains a challenge.

Purpose of the Study:

  • To develop a method for modifying the hydrophilicity of MXene membrane nanochannels.
  • To improve molecular transport and sieving effects in 2D material-based membranes.

Main Methods:

  • Constructed lamellar membranes using poly(ionic liquid)-armored MXene nanosheets.
  • Utilized poly(ionic liquid)s with exchangeable counter anions as a hydrophilicity modifier.
  • Tuned interlayer gallery hydrophobicity through simple anion exchange.

Main Results:

  • Achieved tailorable hydrophilicity in MXene membrane nanochannels.
  • Demonstrated a two-fold improvement in permeance.
  • Obtained high rejection rates (approximately 99%) for water purification.
  • Showcased enhanced molecular transport and sieving effects.

Conclusions:

  • Poly(ionic liquid)s effectively modify MXene membrane hydrophilicity for water purification.
  • Anion exchange provides a facile route to tune membrane performance.
  • This approach offers a new strategy for designing advanced 2D material-based membranes.