Effective and reusable 3D Cu_xS nanocluster structured magnetic adsorbent for mercury extraction from wastewater

The elimination of mercury from polluted water using an effective, cost-economic, and sustainable method was investigated in this work. A modulated multilayer magnetic Hg²⁺ extractor was prepared with a self-assembly engineering that permitting robust anchoring and uniform distribution of the negatively charged 3D Cu_xS nanocluster onto a polydopamine (PDA) covered positively strengthened Fe₃O₄ surface. The developed PAD@Fe₃O₄ supported copper sulfide composite (Cu_xS/PAD@Fe₃O₄) presented an unparalleled Hg²⁺ uptake performance with adsorption capacity of 1394.61 mg/g (without saturation), and extraordinary selectivity with distribution coefficient value K_d of 17419.2 mL/g. A complexation reaction during Hg²⁺ affinity was taken place on Cu_xS/PAD@Fe₃O₄ surface, and almost no components losses occurring during the adsorption. Furthermore, the as-prepared Cu_xS/PAD@Fe₃O₄ micron-adsorbent can be easily magnetic recovery and recycled with hydrochloric acid elution. The purification of 50 L Hg²⁺ containing wastewater, initial concentration of 20 μg/L can be achieved with Cu_xS/PAD@Fe₃O₄ dosage of 0.1 g and treatment cost of 0.077 US $. The outlet Hg²⁺ concentration met drinking water standard of the United States Environmental Protection Agency. The Cu_xS/PAD@Fe₃O₄ magnetic adsorbent can be fabricated cheaply and holds promise for scale-up applications.