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Updated: Sep 24, 2025
Evaluation of the Curing of Adhesive Systems by Rheological and Thermal Testing
Published on: July 3, 2020
Effect of adhesive system, resin cement, heat-pressing technique, and thermomechanical aging on the adhesion between
Burak Yilmaz1, Diogo Gouveia2, Martin Schimmel3
1Associate Professor, Department of Reconstructive Dentistry and Gerodontology, School of Dental Medicine, University of Bern, Bern, Switzerland; Associate Professor, Department of Restorative, Preventive and Pediatric Dentistry, School of Dental Medicine, University of Bern, Bern, Switzerland; Adjunct Professor, Division of Restorative and Prosthetic Dentistry, The Ohio State University, Columbus, Ohio.
Statement Of Problem:
Even though polyetheretherketone (PEEK) has become popular for various prosthetic indications, a standard adhesive protocol to bond the PEEK to titanium bases has not been yet established. How the heat-pressing technique performs in this respect is also not clear.
Purpose:
The purpose of this in vitro study was to investigate the effect of an adhesive system-cement combination, the heat-pressing technique, and thermomechanical aging on the retention force between titanium bases and PEEK specimens.
Material And Methods:
Sixty 9×11×20-mm PEEK specimens with a titanium base slot integrated into the design were milled to simulate an implant-supported PEEK framework for a cantilevered fixed prosthesis. The specimens were assigned to 8 groups (n=10) according to the titanium base primer (MKZ or Monobond) and resin cement (DTK or Multilink hybrid) used and with or without thermomechanical aging. Twenty PEEK specimens were directly heat-pressed on titanium bases, and half of the specimens were not subjected to thermomechanical aging (n=10). For nonaged groups, the PEEK specimen complex was tightened to an implant analog and secured on a custom-made pull-off device. Retention forces were measured by using the pull-off tensile test in a universal testing machine, and the maximum tensile bond strength (MPa) was calculated. The aged groups were subjected to 5000 cycles of thermal aging (5 °C to 55 °C), and the specimens were clamped to load the extension (cantilever) for 1 200 000 cycles with 120 N and 200 N at 1.5-Hz frequency. After aging, the pull-off test was performed for those specimens that survived thermomechanical aging. A nonparametric Kruskal-Wallis test was used to determine whether there was a difference among the groups, followed by pairwise Wilcoxon rank tests with Bonferroni correction. The Wilcoxon rank test was used to analyze the effect of thermomechanical aging in each adhesive system-cement or heat-press group (α=.05 for all tests).
Results:
None of the specimens failed during cyclic loading. According to the Kruskal-Wallis test, the effect of the PEEK-Ti base bonding technique on the retention force in the nonaged (P=.019) and thermomechanically aged groups was significant (P=.010). In the nonaged groups, the heat-pressing technique resulted in a higher retention force than when the specimens were bonded by using the Monobond-Multilink hybrid combination (P=.031). Thermomechanical aging did not significantly affect the results (P>.241). All failures were adhesive, with cement remaining only on the Ti-bases.
Conclusions:
All bonding protocols tested resulted in a stable bond between PEEK and Ti-bases, as all specimens survived thermomechanical aging. The heat-pressing technique resulted in mean bond strength values similar to those obtained with the tested adhesive system-cement combinations with 1 exception; the nonaged heat-pressed groups presented higher bond strength than the Monobond-Multilink hybrid combination. Failure types indicated that the weaker bond was between the PEEK and the cements tested rather than between the titanium base and the cements, regardless of the adhesive system-cement combination.
