Absorption induced ordered ring and inner network structures on a nanoporous substrate

Interaction of colloidal droplets with a porous medium is the key issue for many industrial applications, such as direct-ink-write printing on flexible wearable clothing. In this work, we find a novel pattern of an ordered ring with inner network from a colloidal droplet resting on the nanoporous substrate. Experimental results show that the outward flow caused by the lateral absorption is responsible for the ring structures. The mutual competition between the inward dewetting and the outward flow determines the formation of the inner network pattern. The capillary immersion forces dominate the self-assembly of particles and promote the ordered arrays of the structures.