Facile synthesis of multi-type carbon doped and modified nano-TiO₂ for enhanced visible-light photocatalysis

Nano-TiO₂ is a type of environment-friendly and inexpensive substance that could be used for photocatalytic degradation processes. In this study, the multi-type carbon species doped and modified anatase nano-TiO₂ was innovatively synthesized and developed to overcome the deficiency of common nano-TiO₂ photocatalysts. The multi-type carbon species were derived from tetrabutyl titanate and ethanol as the internal and external carbon sources, respectively. Meanwhile, diverse characterization methods were applied to investigate the morphology and surface properties of the photocatalyst. Finally, the visible-light photocatalytic degradation activity of the collected samples was evaluated by using methyl orange as a model pollutant. The promotion mechanism of multi-type carbon species in the photocatalytic process was also discussed and reported. The results in this work show that the doping and modification of multi-type carbon species successfully narrows the bandgap of nano-TiO₂ to expand the light absorption range, reduces the valence band position to improve the oxidation ability of photogenerated holes, and promotes the separation of photogenerated charge carriers to improve quantum efficiency. In addition, the further modification of the external carbon source can promote the surface adsorption of MO and stabilize the multi-type carbon species on the surface of nano-TiO₂.