Jove
Visualize
Contact Us

Related Concept Videos

Preparation and Reactions of Sulfides02:26

Preparation and Reactions of Sulfides

5.2K
Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
5.2K
Structure and Nomenclature of Thiols and Sulfides02:17

Structure and Nomenclature of Thiols and Sulfides

5.1K
Thiols and sulfides are sulfur analogs of alcohols and ethers, respectively, where the sulfur atom takes the place of the oxygen atom. Thus, thiols are generally represented as RSH, where R is an alkyl substituent and —SH is the functional group. On the other hand, in sulfides, the central sulfur atom is bonded to two hydrocarbon groups on either side. Depending upon the type of group, sulfides can be either symmetrical or asymmetrical. Both thiols and sulfides display a bent geometry,...
5.1K
Resonance02:52

Resonance

56.0K
The Lewis structure of a nitrite anion (NO2−) may actually be drawn in two different ways, distinguished by the locations of the N-O and N=O bonds. 
56.0K
Resonance and Hybrid Structures02:16

Resonance and Hybrid Structures

19.4K
According to the theory of resonance, if two or more Lewis structures with the same arrangement of atoms can be written for a molecule, ion, or radical, the actual distribution of electrons is an average of that shown by the various Lewis structures.
Resonance Structures and Resonance Hybrids
The Lewis structure of a nitrite anion (NO2−) may actually be drawn in two different ways, distinguished by the locations of the N–O and N=O bonds.
19.4K
Oxidation of Phenols to Quinones01:17

Oxidation of Phenols to Quinones

3.5K
In the presence of oxidizing agents, phenols are oxidized to quinones. Quinones can be easily reduced back to phenols using mild reducing agents. The electron-donating hydroxyl group enhances the reactivity of the aromatic ring, enabling oxidation of the ring even in the absence of an α hydrogen.
o-hydroxy phenols are oxidized to o-quinones and p-hydroxy phenols to p-quinones. Such redox reactions involve the transfer of two electrons and two protons. The reversible redox...
3.5K
Structure and Nomenclature of Epoxides02:38

Structure and Nomenclature of Epoxides

6.9K
Cyclic ethers are heterocyclic compounds with an oxygen atom in the ring along with carbon atoms. They are named depending on the number of carbon atoms present in their ring system. Cyclic ethers with a three-membered ring system are called “oxirane”, four-membered ring systems as “oxetane”, five-membered ring systems as “oxolane”, and six-membered ring systems as “oxane”. The cyclic structure of these rings imposes angle strain, and this strain...
6.9K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Synthesis of Vinyl-Containing MQ Copolymers in Active Medium.

Polymers·2026
Same author

Advanced PMSSO Hydrogel Cross-Linked Cyclodextrin Composite Carrier for Enhanced Oral Delivery of Iron to Treat Anemia.

Gels (Basel, Switzerland)·2025
Same author

Investigation of Metallo(organo)siloxane-Polydimethylsiloxane Composites with a High Metallosiloxane Component Content.

Polymers·2025
Same author

Preparation of Concentrated PMMA Suspensions Stabilized by a Green Polysiloxane Surfactant.

Polymers·2025
Same author

Development of a Method for Blocking Polysodiumoxy(methyl)siloxane Obtained in an Alcohol Medium.

Polymers·2025
Same author

Amidated and Aminated PMSSO-Hydrogels as a Promising Enzyme-Sensitive Vehicle for Antianemic Drugs.

Gels (Basel, Switzerland)·2025
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Video

Updated: Sep 24, 2025

Drawing and Hydrophobicity-patterning Long Polydimethylsiloxane Silicone Filaments
07:56

Drawing and Hydrophobicity-patterning Long Polydimethylsiloxane Silicone Filaments

Published on: January 7, 2019

9.0K

Polyphenylsilsesquioxanes. New structures-new properties.

Maxim N Temnikov1, Aziz M Muzafarov1,2

  • 1Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences ul. Vavilova 28 Moscow 119991 Russia aziz@ineos.ac.ru.

RSC Advances
|May 6, 2022
PubMed
Summary
This summary is machine-generated.

This review explores polyphenylsilsesquioxane (PPSQ) synthesis and properties, detailing ladder (l-PPSQ), polyhedral (p-PPSQ), and random polycyclic (r-PPSQ) forms. It also introduces novel acyclic (a-PPSQ), hyperbranched, and globular PPSQ nanogels with unique properties.

More Related Videos

Synthesis of Soft Polysiloxane-urea Elastomers for Intraocular Lens Application
11:49

Synthesis of Soft Polysiloxane-urea Elastomers for Intraocular Lens Application

Published on: March 8, 2019

12.8K
Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
09:37

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

Published on: October 18, 2019

9.7K

Related Experiment Videos

Last Updated: Sep 24, 2025

Drawing and Hydrophobicity-patterning Long Polydimethylsiloxane Silicone Filaments
07:56

Drawing and Hydrophobicity-patterning Long Polydimethylsiloxane Silicone Filaments

Published on: January 7, 2019

9.0K
Synthesis of Soft Polysiloxane-urea Elastomers for Intraocular Lens Application
11:49

Synthesis of Soft Polysiloxane-urea Elastomers for Intraocular Lens Application

Published on: March 8, 2019

12.8K
Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
09:37

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

Published on: October 18, 2019

9.7K

Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Organic Synthesis

Background:

  • Polyphenylsilsesquioxanes (PPSQ) are a class of silicon-organic polymers with diverse structures.
  • Established forms include ladder (l-PPSQ), polyhedral (p-PPSQ), and random polycyclic (r-PPSQ) structures.
  • Understanding their synthesis and properties is crucial for advanced material applications.

Purpose of the Study:

  • To review the synthesis and properties of various polyphenylsilsesquioxane (PPSQ) forms.
  • To compare established PPSQ structures with newly developed acyclic and modified forms.
  • To assess the practical prospects and potential applications of novel PPSQ materials.

Main Methods:

  • Literature review of synthesis methods for l-PPSQ, p-PPSQ, r-PPSQ, and a-PPSQ.
  • Analysis of physicochemical properties of different PPSQ forms.
  • Exploration of modification pathways for acyclic PPSQ.

Main Results:

  • Detailed description of synthesis and properties of l-PPSQ, p-PPSQ, and r-PPSQ.
  • Introduction of recently synthesized acyclic PPSQ (a-PPSQ).
  • Successful modification of a-PPSQ to yield hyperbranched and globular PPSQ (nanogels).

Conclusions:

  • Novel hyperbranched and globular PPSQ forms exhibit distinct physicochemical properties compared to traditional forms.
  • These new PPSQ materials hold significant potential for various practical applications.
  • Further research into their unique properties and applications is warranted.