LiFePO₄-coated LiNi_0.6Co_0.2Mn_0.2O₂ for lithium-ion batteries with enhanced cycling performance at elevated...

LiNi_0.6Co_0.2Mn_0.2O₂ (NCM622) is a highly promising cathode material owing to its high capacity; however, it is characterized by inferior cycling performance and safety problems. We report a novel strategy to improve electrochemical characteristics and safety issues of NCM622 by coating it with LiFePO₄ (LFP). Although having a lower capacity, LFP is a safe and long-cycle cathode material; it is more chemically and thermally stable than NCM622 when exposed to common electrolytes. The LFP-coated NCM622 (NCM@LFP) showed similar rate performance and cycling performance at room temperature compared with the pristine NCM622 under the same conditions. However, significant differences between the NCM622 and NCM@LFP began to emerge at high temperatures. During cycling at 1C for 100 cycles at 55 °C, NCM@LFP showed much improved specific discharge capacity retentions of 92.4%, 90.9%, and 88.2% in the voltage ranges of 3-4.3 V, 3-4.4 V and 3-4.5 V, respectively. The NCM622 suffered significant discharge specific capacity decay under the same condition. In addition, as demonstrated by the delayed exothermic peak in the differential scanning calorimetry (DSC) test, NCM@LFP exhibited excellent thermal stability compared with NCM622, which is critical to battery safety.