Rhodamine B dye is efficiently degraded by polypropylene-based cerium wet catalytic materials

Polypropylene-based cerium wet catalytic materials (Ce/PPNW-g-PAA) were prepared through ultraviolet grafting and ion exchange technology. They were used as effective and reusable heterogeneous catalysts for rhodamine B (RhB) degradation. The physicochemical properties of Ce/PPNW-g-PAA were characterized by Fourier transform infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), specific surface area measurements (BET), and X-ray photoelectron spectroscopy (XPS). The catalytic capacity of the Ce/PPNW-g-PAA-H₂O₂ system for the removal of RhB was tested in comparison with several other systems, which demonstrated that Ce/PPNW-g-PAA effectively promoted the oxidation and degradation of RhB by catalytic wet H₂O₂ oxidation. The results of the RhB degradation showed that Ce/PPNW-g-PAA exhibited excellent degradation performance by achieving a high removal rate for RhB (97.5%) at an initial RhB concentration of 100 mg L^-1, H₂O₂ dosage of 5.0 mmol, Ce/PPNW-g-PAA dosage of 0.15 g L^-1, and initial pH of 5.0 at 298 K. The degradation of RhB by Ce/PPNW-g-PAA conformed to the first-order kinetic reaction model. Consecutive experiments performed with the Ce/PPNW-g-PAA sample showed little activity decay, further confirming the high stability of the catalyst. In addition, the possible degradation mechanism of RhB was also investigated by XPS and electron paramagnetic resonance. The results suggested that Ce³⁺ and hydroxyl radical played important roles during the RhB degradation process.