NiSe₂/CdS composite nanoflakes photocatalyst with enhanced activity under visible light

Degrading organic pollutants using a photocatalyst under visible light is one of the effective ways to solve the increasingly serious environmental pollution problem. In this work, we have loaded a small amount of NiSe₂ nanoflakes on the surface of CdS using a simple and low-cost solvothermal synthesis method. The samples were characterized with detailed X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), electrochemical impedance spectroscopy (EIS), photocurrent, photoluminescence spectrometer (PL), photocatalytic properties, etc. The results show that a 2 mol% load of NiSe₂ increases the rate of degradation of Rhodamine B (RhB) to more than twice the original rate (0.01000 min^-1 versus 0.00478 min^-1). Meanwhile, the sample has excellent stability. The improved photocatalytic properties can be attributed to the face-to-face contact between the nanoflakes, accelerated separation and transfer of photon-generated carriers. This work provides a suitable co-catalyst that can be used to optimize the performance of other photocatalytic materials.