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Updated: Sep 24, 2025

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Layered black phosphorus as a reducing agent - decoration with group 10 elements.

Jan Plutnar1, Zdeněk Sofer1, Martin Pumera1,2,3

  • 1Center for Advanced Functional Nanorobots, Department of Inorganic Chemistry, University of Chemistry and Technology in Prague Technická 5 Prague 6 166 28 Czech Republic martin.pumera@vscht.cz www.twitter.com/PumeraGroup.

RSC Advances
|May 6, 2022
PubMed
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Black phosphorus readily oxidizes, a trait leveraged to modify its surface. Researchers decorated black phosphorus (BP) particles with nickel, palladium, and platinum for advanced material applications.

Area of Science:

  • Materials Science
  • Surface Chemistry
  • Nanotechnology

Background:

  • Black phosphorus (BP) exhibits susceptibility to ambient surface oxidation.
  • This oxidation tendency is typically viewed as a material limitation.
  • However, BP's reductive properties offer opportunities for surface modification and composite material synthesis.

Purpose of the Study:

  • To explore the utilization of black phosphorus's oxidation-prone nature for surface functionalization.
  • To develop a general method for modifying black phosphorus surfaces with metals and their compounds.
  • To prepare black phosphorus-based composite materials with tailored properties.

Main Methods:

  • Decoration of black phosphorus (BP) particles with nickel, palladium, and platinum.

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  • Utilizing BP's reductive properties to form metal phosphides or metallic deposits.
  • Formation of metal deposits as continuous films or discrete nanoparticles on BP surfaces.

    • Main Results:

    • Successfully decorated black phosphorus particles with nickel, palladium, and platinum.
    • Achieved metal deposits in both phosphide and metallic forms.
    • Demonstrated the formation of deposits as films or nanoparticles.
    • Established a versatile method for metal modification of black phosphorus.

    Conclusions:

    • The inherent oxidation susceptibility of black phosphorus can be advantageously employed for surface modification.
    • A general method for decorating black phosphorus with various metals (Ni, Pd, Pt) and their compounds has been established.
    • This approach enables the creation of functionalized black phosphorus materials for diverse applications.