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Updated: Sep 24, 2025

Preparation of N-2-alkoxyvinylsulfonamides from N-tosyl-1,2,3-triazoles and Subsequent Conversion to Substituted Phthalans and Phenethylamines
Published on: January 3, 2018
A convenient method for synthesis of terpyridines via a cooperative vinylogous anomeric based oxidation
Fatemeh Karimi1, Meysam Yarie1, Mohammad Ali Zolfigol1
1Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University Hamedan 6517838683 Iran mzolfigol@yahoo.com.
Abstract:
The presented study is the first report of the synthesis of terpyridines in the presence of a nanomagnetic catalyst instead of harmful reagents. Herein, Fe3O4@O2PO2(CH2)2NH3 +CF3CO2 - as a retrievable nanocatalyst with magnetic properties was applied for the multi-component reaction between acetylpyridine derivatives (2 or 3 or 4-isomer), aryl aldehydes and ammonium acetate under conventional heating conditions in the absence of any solvent. The derived terpyridines were obtained with acceptable yields and brief reaction times via a cooperative vinylogous anomeric based oxidation route. Fe3O4@O2PO2(CH2)2NH3 +CF3CO2 - showed a high capability for recovery and reuse in the mentioned reaction.
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