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Updated: Sep 24, 2025
Methods for Analyzing the Impacts of Natural Uranium on In Vitro Osteoclastogenesis
Published on: January 30, 2018
A multi-technique study of altered granitic rock from the Krunkelbach Valley uranium deposit, Southern Germany
Ivan Pidchenko1,2, Stephen Bauters1,2, Irina Sinenko3
1The Rossendorf Beamline at ESRF - The European Synchrotron CS40220 38043 Grenoble Cedex 9 France kristina.kvashnina@esrf.fr ivan.pidchenko@gmail.com.
Abstract:
Herein, a multi-technique study was performed to reveal the elemental speciation and microphase composition in altered granitic rock collected from the Krunkelbach Valley uranium (U) deposit area near an abandoned U mine, Black Forest, Southern Germany. The former Krunkelbach U mine with 1-2 km surrounding area represents a unique natural analogue site with the rich accumulation of secondary U minerals suitable for radionuclide migration studies from a spent nuclear fuel (SNF) repository. Based on a micro-technique analysis using several synchrotron-based techniques such as X-ray fluorescence analysis, X-ray absorption spectroscopy, powder X-ray diffraction and laboratory-based scanning electron microscopy and Raman spectroscopy, the complex mineral assemblage was identified. While on the surface of granite, heavily altered metazeunerite-metatorbernite (Cu(UO2)2(AsO4)2- (PO4) ·8H2O) microcrystals were found together with diluted coatings similar to cuprosklodowskite (Cu(UO2)2(SiO3OH)2·6H2O), in the cavities of the rock predominantly well-preserved microcrystals close to metatorbernite (Cu(UO2)2(PO4)2·8H2O) were identified. The Cu(UO2)2(AsO4)2- (PO4) ·8H2O species exhibit uneven morphology and varies in its elemental composition, depending on the microcrystal part ranging from well-preserved to heavily altered on a scale of ∼200 μm. The microcrystal phase alteration could be presumably attributed to the microcrystal morphology, variations in chemical composition, and geochemical conditions at the site. The occurrence of uranyl-arsenate-phosphate and uranyl-silicate mineralisation on the surface of the same rock indicates the signatures of different geochemical conditions that took place after the oxidative weathering of the primary U- and arsenic (As)-bearing ores. The relevance of uranyl minerals to SNF storage and the potential role of uranyl-arsenate mineral species in the mobilization of U and As into the environment is discussed.
