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Updated: Sep 24, 2025

In Situ Neutron Powder Diffraction Using Custom-made Lithium-ion Batteries
Published on: November 10, 2014
A promising Mo-based lithium-rich phase for Li-ion batteries
Yongqing Wang1, Haoshen Zhou2,3, Hongbing Ji1
1Fine Chemical Industry Research Institute, School of Chemistry, Sun Yat-Sen University Guangzhou 510275 P. R. China jihb@mail.sysu.edu.cn.
We developed a new composite material, lithium molybdate-lithium nickel manganese cobalt oxide, for advanced lithium-ion batteries. This material shows superior capacity and stability compared to traditional lithium manganese oxide.
Area of Science:
- Materials Science
- Electrochemistry
- Energy Storage
Background:
- Lithium-rich layered oxides are promising cathode materials for high-energy-density lithium-ion batteries.
- Improving capacity and cycle stability remains a key challenge for these materials.
Purpose of the Study:
- To synthesize and characterize a novel composite material based on lithium molybdate and a lithium nickel manganese cobalt oxide.
- To evaluate the electrochemical performance of the composite material as a cathode for lithium-ion batteries.
Main Methods:
- Composite material synthesis via a solid-state reaction.
- Electrochemical testing including charge-discharge cycling and cyclic voltammetry.
Main Results:
- The composite Li2MoO4·LiNi0.4Mn0.4Co0.2O2 material achieved a high practical capacity of 270 mA h g-1.
- The material demonstrated improved capacity retention of 61% after 50 cycles compared to Li2MnO3.
Conclusions:
- The developed composite material offers enhanced electrochemical performance for lithium-ion battery applications.
- This Mo-based material presents a viable alternative to conventional lithium-rich layered oxides.
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