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Updated: Sep 24, 2025

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
Published on: November 29, 2018
Synthetically important ring opening reactions by alkoxybenzenes and alkoxynaphthalenes
1Molecular Synthesis and Drug Discovery Laboratory, Centre of Biomedical Research, Sanjay Gandhi Postgraduate Institute of Medical Sciences Lucknow-226014 India ranadeep@chem.iitkgp.ernet.in.
Abstract:
Alkoxybenzenes and alkoxynaphthalenes, as nucleophiles, have drawn great attention from organic chemists over the decades. Due to their high ring strain, those particular classes of molecules are often used in synthesis by utilizing their properties to undergo facile Friedel-Crafts alkylations. Different isomeric and low or densely substituted alkoxybenzenes are used for synthesis according to the structure of the target molecule. Isomeric methoxybenzenes, are the most commonly used molecule in this regard. This review aims to comprehensively cover the instances of different alkoxy-benzenes/naphthalenes used as nucleophiles for ring opening.
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