Hydrothermal synthesis of Ag-doped ZnO/sepiolite nanostructured material for enhanced photocatalytic activity

This work is devoted to the development of Ag-ZnO/sepiolite photocatalysts as novel nanostructured materials by the immobilization of Ag-doped ZnO on the surface of fibrous clay. Herein, innovative Ag-ZnO/sepiolite photocatalysts were successfully prepared through a simple hydrothermal route using diverse Ag dopant concentrations (2 and 5%). Structural, morphological, and optical properties of the obtained photocatalysts were characterized by XRD, TEM, MEB, and DRS-UV-Vis spectroscopy. The results confirmed that Ag-doped ZnO nanoparticles with a diameter of 10-30 nm are homogeneously distributed on the sepiolite fibers' surface. The silver dopant was effectively incorporated into the zinc oxide, leading to a slight distortion of the hexagonal wurtzite structure and a reduction of the bandgap energy with increased silver doping. The photocatalytic activity towards the degradation of methylene blue (MB) dye was analyzed for all the samples under UV-Vis light. Compared to ZnO alone and undoped ZnO/SEP, the Ag-ZnO/SEP5% nanostructured materials exhibited a significantly improved photocatalytic activity, with full decolorization after 4 h of UV-Vis irradiation (60 W). The photocatalysis of organic pollutants matched well with a pseudo-first-order kinetic. The enhanced photocatalytic activity was ascribed to the low bandgap energy (3 eV), the reduction of the recombination of electron hole, and the sepiolite support.