Related Experiment Video For Cr(6+)
Updated: Sep 24, 2025
Novel Techniques for Observing Structural Dynamics of Photoresponsive Liquid Crystals
Published on: May 29, 2018
A novel liquid crystal resonance Rayleigh scattering spectral probe for determination of trace Cr6
Shengfu Zhi1, Chongning Li1, Zhiliang Jiang2
1School of Public Health, Guilin Medical University, Guilin 541199, China; Guangxi Key Laboratory of Environmental Pollution Control Theory and Technology for Science and Education Combined with Science and Technology Innovation Base, Guilin 541006, China.
Abstract:
Hexavalent chromium (Cr6+) has strong oxidizing property and toxicity. It has been identified as a carcinogen with obvious carcinogenic effect by the International Anti-cancer Research Center. Therefore, it has a great significance to establish a simple and sensitive method for Cr6+. In the solution, liquid crystal (LC) trans, trans-4-(3,4-difluorophenyl)-4'-n-pentylbicyclohexyl (DP) exhibits strong resonance Rayleigh scattering (RRS) effect due to formation DP nanoparticles. It was used firstly as nanoprobe, to establish a simple and sensitive RRS energy transfer (RRS-ET) method for the determination of trace Cr6+ in water samples. The Cr6+ reacts with diphenylcarbazide (DCB) to produce purple complex. It is adsorbed on the nanoprobe surface, the purple complex as energy receptor and DP as energy donor to produce RRS-ET phenomenon, to make the RRS signal of 370 nm decreasing. In the range of 3-30 nmol/L Cr6+, with the increase of concentration, the RRS signal decreased linearly at 370 nm, with a detection limit of 0.49 nmol/L. This new RRS-ET method was applied to the determination of Cr6+ in water samples, with recovery of 96.0-104.7% and the relative standard deviation (RSD) of 4.44-9.98%.
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