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Updated: Sep 24, 2025

Confocal Imaging of Confined Quiescent and Flowing Colloid-polymer Mixtures
Published on: May 20, 2014
Defect-mediated colloidal interactions in a nematic-phase discotic solvent
Aurora D González-Martínez1, Marco A Chávez-Rojo2, Edward J Sambriski3
1Departamento de Física, Universidad Autónoma Metropolitana-Iztapalapa Avenida San Rafael Atlixco No. 186, Colonia Vicentina, Delegación Iztapalapa Mexico City 09340 Mexico jamr.uam@gmail.com.
Abstract:
Interactions between colloidal inclusions dispersed in a nematic discotic liquid-crystalline solvent were investigated for different solute-solvent coupling conditions. The solvent was treated at the level of Gay-Berne discogens. Colloidal inclusions were coupled to the solvent with a generalized sphere-ellipsoid interaction potential. Energy strengths were varied to promote either homeotropic or planar mesogenic anchoring. Colloid-colloid interactions were modeled using a soft, excluded-volume contribution. Single-colloid and colloid-pair samples were evolved with Molecular Dynamics simulations. Equilibrium trajectories were used to characterize structural and dynamical properties of topological defects arising in the mesomorphic phase due to colloidal inclusions. Boojums were observed with planar anchoring, whereas Saturn rings were obtained with homeotropic anchoring. The manner in which these topological defects drive colloidal interactions was assessed through a free energy analysis, taking into account the relative orientation between a colloidal dyad and the nematic-field director. The dynamical behavior of defects was qualitatively surveyed from equilibrium trajectories borne from computer simulations.
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A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
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