Hydrogen peroxide-assisted synthesis of oxygen-doped carbon nitride nanorods for enhanced photocatalytic hydrogen...

Polymer-derived carbon nitrides based photocatalysts are very promising for solar water splitting, CO₂ reduction and environmental remediation. However, these photocatalysts still suffer from low visible light utilization efficiency, rapid recombination of photogenerated charge carriers and slow transfer kinetics. Herein, we report a hydrogen peroxide-assisted hydrothermal strategy to synthesize one-dimensional oxygen-doped carbon nitrides (OCN) for photocatalytic hydrogen evolution. A possible self-assembly mechanism is discussed. Experimental results and theoretical calculations indicate that the as-synthesized one-dimensional OCN possess narrowed band gap energy and optimized band structure, which may allow more effective visible-light harvesting and facilitate photogenerated electron-hole pair separation and transfer. As a result, the photocatalytic hydrogen evolution rates improve from 10.4 μmol h^-1 to 74.0 μmol h^-1 under visible light (λ > 400 nm), which is among the best of the reported CN-based photocatalysts for visible-light-driven hydrogen evolution. This study provides a new avenue toward the development of highly efficient carbon nitrides based photocatalysts for photocatalytic applications.