Ionic liquid-based electrolytes for CO₂ electroreduction and CO₂ electroorganic transformation

CO₂ is an abundant and renewable C1 feedstock. Electrochemical transformation of CO₂ can integrate CO₂ fixation with renewable electricity storage, providing an avenue to close the anthropogenic carbon cycle. As a new type of green and chemically tailorable solvent, ionic liquids (ILs) have been proposed as highly promising alternatives for conventional electrolytes in electrochemical CO₂ conversion. This review summarizes major advances in the electrochemical transformation of CO₂ into value-added carbonic fuels and chemicals in IL-based media in the past several years. Both the direct CO₂ electroreduction (CO₂ER) and CO₂-involved electroorganic transformation (CO₂EOT) are discussed, focusing on the effect of electrocatalysts, IL components, reactor configurations and operating conditions on catalytic activity, selectivity and reusability. The reasons for the enhanced CO₂ conversion performance by ILs are also discussed, providing guidance for the rational design of novel IL-based electrochemical processes for CO₂ conversion. Finally, the critical challenges remaining in this research area and promising directions for future research are proposed.