Slow magnetic relaxation for cobalt(II) complexes in axial bipyramidal environment: an S = 1/2 spin case

A new family of magnetically mononuclear cobalt(II) complexes with formula [{Ni^II(L)Co^II(H₂O)₂(MeOH)}{Ni^II(L)}₂](ClO₄)₂ where H₂L1 = bis(N,N'-bis(3-methoxysalicylidene)ethylene-1,2-diamine) (1), H₂L2 = bis(N,N'-bis(3-methoxysalicylidene)propane-1,2-diamine) (2) and [{Cu^II(L4)}₂Co^II](ClO₄)₂ (3) where H₂L4 = bis(N,N'-bis(3-ethoxysalicylidene)cyclohexane-1,2-diamine) have been obtained employing non chiral or enantiomerically pure Schiff bases. The structural studies have been carried out by single crystal X-ray and powder diffraction. Dynamic magnetic studies indicate that some members of this family present field induced slow relaxation of the magnetization and its response has been compared with the magnetically diluted [Zn_0.9Co_0.1] complex 1D. Ultra-low frequency Raman spectroscopy has been used to relate the slow relaxation with lattice vibrations.