Preparation of silica coatings with continuously adjustable refractive indices and wettability properties via sol-gel...

Silica coatings with continuously adjustable refractive indices and wettability properties were prepared through a sol-gel base-catalyzed process. Adjustment of the molar ratio of water (H₂O) to tetraethylorthosilicate (TEOS) was utilized to change the hydrolysis degree of the precursors, and hence change the morphology of the silica particles. With the increase in the H₂O/TEOS molar ratio, the morphology of the silica particles changed from a linear net-work structure to a bead-like structure and then to a granular particle structure. A particle growth mechanism was proposed and verified by characterization. As the H₂O/TEOS molar ratio increased from 0.3 to 21.0, the refractive indices of the silica coatings increased from 1.132 to 1.328. Meanwhile, a varied H₂O/TEOS molar ratio also modulated the surface wettability of the silica coatings. The static water angle of the silica coatings decreased from 145° to 6° by increasing the H₂O/TEOS molar ratio from 0.3 to 21.0. Different hydrophilic and hydrophobic coatings could be obtained by simply controlling the H₂O/TEOS molar ratio. Silica coatings with different refractive indices and hydrophobic (or hydrophilic) properties were obtained at different H₂O/TEOS molar ratios.