Related Experiment Video
Updated: Sep 23, 2025
Surface Properties of Synthesized Nanoporous Carbon and Silica Matrices
Published on: March 27, 2019
Insight into the significant roles of microstructures and functional groups on carbonaceous surfaces for acetone
Xinning Yu1, Shaojun Liu1,2, Guoxin Lin1
1State Key Laboratory of Clean Energy Utilization, Zhejiang University Hangzhou 310027 China xgao1@zju.edu.cn.
Abstract:
To understand the roles of pore structures and functional groups on acetone adsorption, activated carbons (ACs) with different properties were obtained by surface modification. XRD, SEM, TEM and nitrogen adsorption were used to identify the structural characteristics of the ACs, while TG-DTA, FTIR, XPS and Boehm titration were applied to analyse the surface chemistries. The microporous surface areas showed a positive linear correlation to the acetone adsorption amounts, and increasing the carboxylic groups could improve the uptake of strongly adsorbed acetone. HNO3 modified AC (AC-N) was found to exhibit an excellent adsorption capacity of 5.49 mmol g-1, which might be attributed to the developed microporous structures and abundant carboxylic groups. The desorption activation energies (E d) of strongly adsorbed acetone on AC-N and AC were both determined to be 81.6 kJ mol-1, indicating the same adsorption sites on different activated carbons, suspected to be carboxylic groups. The possible adsorption mechanism of acetone on carbonaceous surfaces was also proposed.
More Related Videos
11:38In situ FTIR Spectroscopy as a Tool for Investigation of Gas/Solid Interaction: Water-Enhanced CO2 Adsorption in UiO-66 Metal-Organic Framework
Published on: February 1, 2020
10:44Preparation of Biomass-based Mesoporous Carbon with Higher Nitrogen-/Oxygen-chelating Adsorption for CuII Through Microwave Pre-Pyrolysis
Published on: February 12, 2019
Related Concept Videos
01:24Acetals and Thioacetals as Protecting Groups for Aldehydes and Ketones
In the presence of multiple functional groups, when selective reduction of one group over the other is desired, groups like aldehydes and ketones that form acetals...
01:04Structures of Aldehydes and Ketones
In aldehydes (Figures 1a and 1b),...
01:23Protecting Groups for Aldehydes and Ketones: Introduction
02:22Overview of Advanced Functional Groups
Functional groups are groups of atoms with specific chemical properties that occur within organic molecules and are sometimes denoted as “R”. Functional groups can “functionalize” a compound by enabling it to adopt different physical and chemical properties.
Types of Advanced Functional Groups
The table below summarizes some of the major functional groups in organic chemistry.
02:37Structure and Physical Properties of Alkynes
In nature, compounds containing both carbon and hydrogen are known as "hydrocarbons". Aliphatic hydrocarbons are compounds whose molecules contain saturated single bonds (i.e., alkanes) or unsaturated double or triple bonds. Alkenes contain carbon–carbon double bonds and have a structural formula CnH2n. Unsaturated hydrocarbons containing carbon–carbon triple bonds are called "alkynes" and are structurally represented by the formula CnH2n-2.
The...
02:08Introduction to Functional Groups
Functional groups are group of atoms with specific chemical properties that occur within organic molecules and sometimes denoted as “R”. Functional groups are found along the carbon backbone of macromolecules can form chains or rings of carbon atoms. Functional groups can “functionalize” a compound by enabling it to adopt different physical and chemical properties.
Types of common functional groups
The table below summarizes some of the major functional...