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Efficient removal of pentachlorophenol from aqueous solution by 4-tert-butylcalix[8]arene modified thermally

Ying Guo1,2, Bing Liao3, Kun Wang1,2

  • 1Key Laboratory of Cellulose and Lignocellulosics Chemistry, Guangzhou Institute of Chemistry, Chinese Academy of Sciences Guangzhou 510650 People's Republic of China panghao@gic.ac.cn.

RSC Advances
|May 11, 2022
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Simple aryl halides do not react with nucleophiles under normal conditions. However, the reaction can proceed under drastic conditions involving high temperatures and high pressure to give the substituted products. For example, chlorobenzene is converted to phenol using aqueous sodium hydroxide at 350 °C under high pressure by the Dow process. The reaction follows an elimination-addition mechanism involving a benzyne intermediate. Here, the chloride ion is eliminated to generate the benzyne...