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Updated: Sep 23, 2025
Author Spotlight: Functionalizing Metal-Organic Frameworks: Advancements, Challenges, and the Power of Post-Synthetic Ligand Exchange
Published on: June 23, 2023
Synthesis and properties of a POM-based trinuclear copper(ii) triazole framework
Li Xu1, Ying Lu1, Liping Huang1
1Key Laboratory of Polyoxometalate Science of the Ministry of Education, College of Chemistry, Northeast Normal University Changchun Jilin 130024 China liusx@nenu.edu.cn +86-431-85099328.
Abstract:
A novel POM-based trinuclear copper(ii) triazole framework, namely, [H2{Cu6(trz)6(μ3-OH)2}Mo5O18]·3H2O (1) was isolated using a hydrothermal method, which displays a 3D network constructed from trinuclear copper(ii) units and triazole ligands with [Mo5O18]6- anions as templates. 1 has been identified by single crystal X-ray diffraction, elemental analysis, thermogravimetric analysis, powder X-ray diffraction and FT-IR. Magnetic studies indicate that antiferromagnetic interactions exist in 1. In addition, 1 exhibits good Lewis acid catalytic activity for the synthesis of cyclohexanone ethylene ketal with 95% conversion. The HOMO-LUMO gap (E g) of 1 is 2.34 eV calculated using the Kubelka-Munk equation (Fhν)0.5, indicating that its forbidden bandwidth belongs to the semiconductor category. Visible-light photodegradation of RhB catalyzed by 1 was investigated, which shows high activity with an above 98% degradation rate.
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