Nickel metal-organic frameworks for visible-light CO₂ reduction under mild reaction conditions

Photochemical CO₂ conversion into carbon fuel is a promising route to explore renewable energy and relieve climate change. However, it is still a key challenge to achieve high selectivity to CO and simultaneously achieve high conversion efficiency in photochemical CO₂ reduction. Herein, we demonstrate the effect of Ni metal centers as catalytic active sites for the photocatalytic conversion of CO₂ to CO by designing and constructing Ni metal-organic framework (Ni-MOF) materials. In pure CO₂, Ni-MOF catalyst exhibits outstanding performance for visible-light-driven reductive CO₂ deoxygenation with a high CO evolution rate of 19.13 μmol h^-1 (per 1 mg of catalyst) and CO selectivity of 91.4%, which exceeds those of most reported systems. Upon using isostructural Co-MOF as the catalyst to replace Ni-MOF, a moderate performance towards CO₂ photoreduction and low CO selectivity (40.1%) were observed, implying that the performance of CO₂ photoreduction and CO selectivity are dependent on unsaturated metal centers.