Anchoring Black Phosphorus Quantum Dots on Fe-Doped W₁₈ O₄₉ Nanowires for Efficient Photocatalytic Nitrogen Fixation

Herein, we demonstrate that the surface anchoring of black phosphorus quantum dots (BPQDs) and bulk iron-doping in W₁₈ O₄₉ nanowires significantly promotes the photocatalytic activity toward N₂ fixation into NH₃ . More specifically, a NH₃ production rate of up to 187.6 μmol g^-1  h^-1 could be achieved, nearly one order of magnitude higher than that of pristine W₁₈ O₄₉ (18.9 μmol g^-1  h^-1 ). Comprehensive experiments and density-functional theory calculations reveal that Fe-doping could enhance the reducing ability of photo-generated electrons by decreasing the work function and elevating the defect band (d-band) centers. Additionally, the surface BPQDs anchoring could facilitate the N₂ adsorption/activation owing to the increased adsorption energy and advantaged W-P dimer bonding-mode. Therefore, synergizing the surface BPQD anchoring and bulk Fe-doping remarkably enhanced the photocatalytic activity of W₁₈ O₄₉ nanowires for NH₃ production.